There is no 9–6 overlap. Stretching to 07:00–21:00 on both sides gives you 07:00–10:00 Sao Paulo time:
07:00 you → 18:00 Singapore
08:00 you → 19:00 Singapore
09:00 you → 20:00 Singapore
09:00→20:00outside Singapore working hours
10:00→21:00outside Singapore working hours
11:00→22:00outside Singapore working hours
12:00→23:00outside Singapore working hours
13:00→00:00next day · outside Singapore working hours
14:00→01:00next day · outside Singapore working hours
15:00→02:00next day · outside Singapore working hours
16:00→03:00next day · outside Singapore working hours
17:00→04:00next day · outside Singapore working hours
Working hours assumed 09:00–18:00 local. Offsets include daylight saving where it applies, so this shifts through the year.